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Issue 50, 2014

Hydrotrifluoromethylthiolation of α-diazo esters – synthesis of α-SCF3 substituted esters

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Abstract

A practical protocol for hydrotrifluoromethylthiolation of diazo compounds has been developed. A range of diazo compounds in combination with a nucleophilic SCF3 source provided access to valuable trifluoromethylthiolated compounds. Furthermore, a methodology for the first double trifluoromethylthiolation was developed.

Graphical abstract: Hydrotrifluoromethylthiolation of α-diazo esters – synthesis of α-SCF3 substituted esters

Supplementary files

Article information


Submitted
19 Mar 2014
Accepted
01 May 2014
First published
13 May 2014

Chem. Commun., 2014,50, 6617-6619
Article type
Communication

Hydrotrifluoromethylthiolation of α-diazo esters – synthesis of α-SCF3 substituted esters

Q. Lefebvre, E. Fava, P. Nikolaienko and M. Rueping, Chem. Commun., 2014, 50, 6617 DOI: 10.1039/C4CC02060J

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