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Issue 44, 2014
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Dehydrogenation of a tertiary amine-borane by a rhenium complex

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Abstract

Photolysis of CpRe(CO)3 in the presence of H3BNEt3 yields the trans-CpRe(CO)2(H)2 complex. This preliminary finding presents a rare example of transition metal mediated dehydrogenation of a tertiary amine-borane and suggests that the abstracted hydrogens may be stored in the form of metal hydride complexes.

Graphical abstract: Dehydrogenation of a tertiary amine-borane by a rhenium complex

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Publication details

The article was received on 09 Mar 2014, accepted on 14 Apr 2014 and first published on 15 Apr 2014


Article type: Communication
DOI: 10.1039/C4CC01771D
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Chem. Commun., 2014,50, 5874-5877

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    Dehydrogenation of a tertiary amine-borane by a rhenium complex

    S. Muhammad, S. Moncho, E. N. Brothers and A. A. Bengali, Chem. Commun., 2014, 50, 5874
    DOI: 10.1039/C4CC01771D

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