Issue 49, 2014

An unexpected role of the monodentate ligand in photocatalytic hydrogen production of the pentadentate ligand-based cobalt complexes

Abstract

The dissociation of one pyridine of a pentadentate ligand (N4Py) from the Co centre was found to be responsible for the formation of a Co(III) hydride species, an indispensable intermediate for photocatalytic proton reduction.

Graphical abstract: An unexpected role of the monodentate ligand in photocatalytic hydrogen production of the pentadentate ligand-based cobalt complexes

Supplementary files

Article information

Article type
Communication
Submitted
26 Feb 2014
Accepted
29 Mar 2014
First published
31 Mar 2014

Chem. Commun., 2014,50, 6520-6522

An unexpected role of the monodentate ligand in photocatalytic hydrogen production of the pentadentate ligand-based cobalt complexes

J. Xie, Q. Zhou, C. Li, W. Wang, Y. Hou, B. Zhang and X. Wang, Chem. Commun., 2014, 50, 6520 DOI: 10.1039/C4CC01471E

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