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Issue 39, 2014
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[4+2+2] Cycloaddition catalyzed by a new cationic rhodium–bisphosphine monooxide complex

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Abstract

A rhodium–BozPHOS based complex is reported. This complex is competent in catalyzing the [4+2+2] cycloisomerization of cyclooctatrienes in moderate to good yields. The X-ray crystal structure of this complex is reported, along with formation of both bicyclic and tricyclic cyclooctatrienes.

Graphical abstract: [4+2+2] Cycloaddition catalyzed by a new cationic rhodium–bisphosphine monooxide complex

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Supplementary files

Article information


Submitted
19 Feb 2014
Accepted
26 Mar 2014
First published
26 Mar 2014

Chem. Commun., 2014,50, 5007-5010
Article type
Communication
Author version available

[4+2+2] Cycloaddition catalyzed by a new cationic rhodium–bisphosphine monooxide complex

G. M. R. Canlas and S. R. Gilbertson, Chem. Commun., 2014, 50, 5007
DOI: 10.1039/C4CC01320D

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