n-Bu4NI/TBHP-catalyzed direct amination of allylic and benzylic C(sp3)–H with anilines under metal-free conditions

Xusheng Zhang; Min Wang; Pinhua Li; Lei Wang

doi:10.1039/C4CC01189A

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n-Bu₄NI/TBHP-catalyzed direct amination of allylic and benzylic C(sp³)–H with anilines under metal-free conditions†

Xusheng Zhang,^a Min Wang,*^a Pinhua Li^a and Lei Wang*^ab

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* Corresponding authors

^a Department of Chemistry, Huaibei Normal University, Huaibei, Anhui 235000, P. R. China
E-mail: leiwang@chnu.edu.cn
Fax: +86-561-309-0518
Tel: +86-561-380-2069

^b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, P. R. China

Abstract

A novel and efficient n-Bu₄NI/TBHP-catalyzed direct amination of allylic and benzylic C(sp³)–H with anilines to form N-substituted anilines under metal-free conditions has been developed.

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Article information

DOI: https://doi.org/10.1039/C4CC01189A
Article type: Communication
Submitted: 14 Feb 2014
Accepted: 03 Jun 2014
First published: 04 Jun 2014

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Chem. Commun., 2014,50, 8006-8009

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n-Bu₄NI/TBHP-catalyzed direct amination of allylic and benzylic C(sp³)–H with anilines under metal-free conditions

X. Zhang, M. Wang, P. Li and L. Wang, Chem. Commun., 2014, 50, 8006 DOI: 10.1039/C4CC01189A

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