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Issue 28, 2014
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Slow relaxation in the first penta-aza Dy(iii) macrocyclic complex

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Abstract

A new macrocyclic complex DyCl3(LN5)·4H2O (1) has been prepared in which the Dy(III) ion is equatorially bound by an N5-donor macrocycle (LN5). Ac susceptibility data reveal slow relaxation of the magnetisation in zero field below 15 K with a distribution of relaxation rates.

Graphical abstract: Slow relaxation in the first penta-aza Dy(iii) macrocyclic complex

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Article information


Submitted
04 Feb 2014
Accepted
20 Feb 2014
First published
20 Feb 2014

Chem. Commun., 2014,50, 3741-3743
Article type
Communication
Author version available

Slow relaxation in the first penta-aza Dy(III) macrocyclic complex

E. L. Gavey, Y. Beldjoudi, J. M. Rawson, T. C. Stamatatos and M. Pilkington, Chem. Commun., 2014, 50, 3741
DOI: 10.1039/C4CC00930D

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