Issue 47, 2014
From the journal:

Chemical Communications

Poly(trifluoromethyl)azulenes: structures and acceptor properties†

Tyler T. Clikeman,a   Eric V. Bukovsky,a   Igor V. Kuvychko,a   Long K. San,a   Shihu H. M. Deng,b   Xue-Bin Wang,*b   Yu-Sheng Chen,c   Steven H. Strauss*a  and  Olga V. Boltalina*a  

* Corresponding authors

a Department of Chemistry, Colorado State University, Fort Collins, CO 80523, USA
E-mail: steven.strauss@colostate.edu, olga.boltalina@colostate.edu
Fax: +1-970-491-1801
Tel: +1-970-491-5088

b Physical Sciences Division, Pacific Northwest National Laboratory, P.O. Box 999, MS K8-88, Richland, Washington 99352, USA

c ChemMatCARS, University of Chicago Advanced Photon Source, Argonne, IL 60439, USA

Abstract

Six new poly(trifluoromethyl)azulenes prepared in a single high-temperature reaction exhibit strong electron accepting properties in the gas phase and in solution and demonstrate the propensity to form regular π-stacked columns in donor–acceptor crystals when mixed with pyrene as a donor.

Graphical abstract: Poly(trifluoromethyl)azulenes: structures and acceptor properties

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Article information

DOI
https://doi.org/10.1039/C4CC00510D
Article type
Communication
Submitted
21 Jan 2014
Accepted
08 Apr 2014
First published
08 Apr 2014

Chem. Commun., 2014,50, 6263-6266

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Poly(trifluoromethyl)azulenes: structures and acceptor properties

T. T. Clikeman, E. V. Bukovsky, I. V. Kuvychko, L. K. San, S. H. M. Deng, X. Wang, Y. Chen, S. H. Strauss and O. V. Boltalina, Chem. Commun., 2014, 50, 6263 DOI: 10.1039/C4CC00510D

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