Issue 28, 2014
From the journal:

Chemical Communications

Solid-state conversion of a MOF to a metal-organo polymeric framework (MOPF) via [2+2] cycloaddition reaction†

In-Hyeok Park,a   Anjana Chanthapally,b   Hyeong-Hwan Lee,a   Hong Sheng Quah,b   Shim Sung Lee*a  and  Jagadese J. Vittal*ab  

* Corresponding authors

a Department of Chemistry and Research Institute of Natural Science, Gyeongsang National University, Jinju 660-701, S. Korea
E-mail: sslee@gnu.ac.kr
Fax: +82 55-753-7614
Tel: +82 55-772-1483

b Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543
E-mail: chmjjv@nus.edu.sg
Fax: +65 6779 1691
Tel: +65 6516 2975

Abstract

The bpeb ligands aligned in a slip-stacked manner in a two-fold interpenetrated non-porous metal–organic framework (MOF) [Zn2(bpeb)(bdc)(fa)2] undergo [2+2] cycloaddition reaction in a single-crystal to single-crystal manner to a non-interpenetrated 3D structure with a new topology comprising an organic polymer ligand and a 2D coordination polymer.

Graphical abstract: Solid-state conversion of a MOF to a metal-organo polymeric framework (MOPF) via [2+2] cycloaddition reaction

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DOI
https://doi.org/10.1039/C4CC00228H
Article type
Communication
Submitted
10 Jan 2014
Accepted
22 Jan 2014
First published
23 Jan 2014
This article is Open Access
Creative Commons BY license

Chem. Commun., 2014,50, 3665-3667

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Solid-state conversion of a MOF to a metal-organo polymeric framework (MOPF) via [2+2] cycloaddition reaction

I. Park, A. Chanthapally, H. Lee, H. S. Quah, S. S. Lee and J. J. Vittal, Chem. Commun., 2014, 50, 3665 DOI: 10.1039/C4CC00228H

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