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Issue 24, 2014
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Single-crystal-to-single-crystal transformation of a two-dimensional coordination polymer through highly selective [2+2] photodimerization of a conjugated dialkene

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Abstract

A 2D network [Zn4(OH)2(5-NO2-1,3-BDC)2(5-NO2-1,3-HBDC)2(ppene)2]n underwent a highly selective [2+2] photodimerization reaction upon UV irradiation. The coordination polymer retains its single crystallinity after photoreaction.

Graphical abstract: Single-crystal-to-single-crystal transformation of a two-dimensional coordination polymer through highly selective [2+2] photodimerization of a conjugated dialkene

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Article information


Submitted
24 Dec 2013
Accepted
02 Feb 2014
First published
03 Feb 2014

Chem. Commun., 2014,50, 3173-3175
Article type
Communication

Single-crystal-to-single-crystal transformation of a two-dimensional coordination polymer through highly selective [2+2] photodimerization of a conjugated dialkene

D. Liu, H. Wang, B. F. Abrahams and J. Lang, Chem. Commun., 2014, 50, 3173
DOI: 10.1039/C3CC49749F

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