Issue 34, 2014

High-turnover visible-light photoreduction of CO2 by a Re(i) complex stabilized on dye-sensitized TiO2

Abstract

Hybrid systems prepared by fixing a Re(I) complex and a dye on three types of TiO2 nanoparticles in two different ways commonly revealed persistent photocatalysis of the CO2 reduction to CO with no levelling-off tendency under visible-light irradiation in DMF, giving a turnover number of ≥435.

Graphical abstract: High-turnover visible-light photoreduction of CO2 by a Re(i) complex stabilized on dye-sensitized TiO2

Supplementary files

Article information

Article type
Communication
Submitted
24 Dec 2013
Accepted
07 Mar 2014
First published
11 Mar 2014

Chem. Commun., 2014,50, 4462-4464

Author version available

High-turnover visible-light photoreduction of CO2 by a Re(I) complex stabilized on dye-sensitized TiO2

E. Ha, J. Chang, S. Byun, C. Pac, D. Jang, J. Park and S. O. Kang, Chem. Commun., 2014, 50, 4462 DOI: 10.1039/C3CC49744E

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