Issue 17, 2014

Gold(i)-catalysed [1,3] O→C rearrangement of allenyl ethers

Abstract

A simple and rapid access to the α-substituted acryl aldehydes has been provided by developing a gold-catalysed [1,3] rearrangement of the allenyl ethers importantly with a record turnover frequency of 4600 h−1 (at 0.05 mol% of the catalyst concentration) in homogeneous gold(I) catalysis.

Graphical abstract: Gold(i)-catalysed [1,3] O→C rearrangement of allenyl ethers

Supplementary files

Article information

Article type
Communication
Submitted
19 Dec 2013
Accepted
02 Jan 2014
First published
06 Jan 2014

Chem. Commun., 2014,50, 2152-2154

Author version available

Gold(I)-catalysed [1,3] O→C rearrangement of allenyl ethers

C. N. Kona and C. V. Ramana, Chem. Commun., 2014, 50, 2152 DOI: 10.1039/C3CC49629E

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