Issue 30, 2014
From the journal:

Chemical Communications

Preparation and structure of acenaphthylene-1,2-diyldi(9-acridine) derivatives with a long C[double bond, length as m-dash]C bond†

Takashi Takeda,*a   Yasuto Uchimura,b   Hidetoshi Kawai,c   Ryo Katoono,b   Kenshu Fujiwarab  and  Takanori Suzuki*b  

* Corresponding authors

a Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, Sendai, Miyagi 980-8577, Japan
E-mail: takeda@tagen.tohoku.ac.jp
Fax: +81-22-217-5654
Tel: +81-22-217-5655

b Department of Chemistry, Faculty of Science, Hokkaido University, Sapporo, Hokkaido 060-0810, Japan
E-mail: tak@mail.sci.hokudai.ac.jp
Fax: +81-11-706-2714
Tel: +81-11-706-2714

c Department of Chemistry, Faculty of Science, Tokyo University of Science, Shinjuku, Tokyo 162-8601, Japan

Abstract

Due to purely steric effects of acridine units, acenaphthylene-1,2-diyldi(9-acridine) has a long C[double bond, length as m-dash]C bond [1.3789(19) Å] while maintaining its sp2 hybridized nature and bond order.

Graphical abstract: Preparation and structure of acenaphthylene-1,2-diyldi(9-acridine) derivatives with a long C [[double bond, length as m-dash]] C bond

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Article information

DOI
https://doi.org/10.1039/C3CC49573F
Article type
Communication
Submitted
18 Dec 2013
Accepted
19 Jan 2014
First published
20 Jan 2014
This article is Open Access
Creative Commons BY license

Chem. Commun., 2014,50, 3924-3927

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Preparation and structure of acenaphthylene-1,2-diyldi(9-acridine) derivatives with a long C[double bond, length as m-dash]C bond

T. Takeda, Y. Uchimura, H. Kawai, R. Katoono, K. Fujiwara and T. Suzuki, Chem. Commun., 2014, 50, 3924 DOI: 10.1039/C3CC49573F

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