Issue 18, 2014
From the journal:

Chemical Communications

Pd/C-catalyzed direct formylation of aromatic iodides to aryl aldehydes using carbon dioxide as a C1 resource†

Bo Yu,a   Yanfei Zhao,a   Hongye Zhang,a   Jilei Xu,a   Leiduan Hao,a   Xiang Gaoa  and  Zhimin Liu*a  

* Corresponding authors

a Beijing National Laboratory for Molecular Sciences, Key Laboratory of Colloid, Interface and Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
E-mail: liuzm@iccas.ac.cn

Abstract

Pd/C-catalyzed direct formylation of aromatic iodides to aryl aldehydes using CO2 as a C1 resource was realized for the first time in the presence of hydrosilanes and base DBU under mild conditions, giving a series of aldehydes in good yields.

Graphical abstract: Pd/C-catalyzed direct formylation of aromatic iodides to aryl aldehydes using carbon dioxide as a C1 resource

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Article information

DOI
https://doi.org/10.1039/C3CC49365B
Article type
Communication
Submitted
10 Dec 2013
Accepted
08 Jan 2014
First published
08 Jan 2014

Chem. Commun., 2014,50, 2330-2333

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Pd/C-catalyzed direct formylation of aromatic iodides to aryl aldehydes using carbon dioxide as a C1 resource

B. Yu, Y. Zhao, H. Zhang, J. Xu, L. Hao, X. Gao and Z. Liu, Chem. Commun., 2014, 50, 2330 DOI: 10.1039/C3CC49365B

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