SCHEDULED MAINTENANCE
A Pd(0)-catalyzed intramolecular aryldifluoromethylation of activated alkenes under mild reaction conditions has been developed. This reaction provides a new method for construction of a variety of difluoromethylated oxindoles. Mechanistic investigations indicate that a difluoromethyl radical, which was triggered by Pd(0), initiated the cascade sequence through an addition to the alkene.
J. Wang, Y. Su, F. Yin, Y. Bao, X. Zhang, Y. Xu and X. Wang, Chem. Commun., 2014, 50, 4108 DOI: 10.1039/C3CC49315F
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