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Issue 12, 2014
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A simple route to azaborinylphosphines: isoelectronic B–N analogues of arylphosphine ligands

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Abstract

Azaborinylphosphines are readily prepared by the reaction of silylphosphines with a chloroborane under mild conditions; they are shown to contain P–B bonds that are sufficiently robust to allow these ligands to be used in homogeneous catalysis.

Graphical abstract: A simple route to azaborinylphosphines: isoelectronic B–N analogues of arylphosphine ligands

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Publication details

The article was received on 25 Nov 2013, accepted on 06 Dec 2013 and first published on 09 Dec 2013


Article type: Communication
DOI: 10.1039/C3CC49000A
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Chem. Commun., 2014,50, 1432-1434
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    A simple route to azaborinylphosphines: isoelectronic B–N analogues of arylphosphine ligands

    J. A. Bailey, M. F. Haddow and P. G. Pringle, Chem. Commun., 2014, 50, 1432
    DOI: 10.1039/C3CC49000A

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