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Issue 9, 2014
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Stepwise addition of difluorocarbene to a transition metal centre

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Abstract

The Ruppert–Prakash reagent (Me3SiCF3) is used to introduce difluorocarbene (CF2) and tetrafluoroethylene (TFE) ligands to cobalt(I) metal centres, whereby the TFE ligand is generated via [2+1] cycloaddition between [Co][double bond, length as m-dash]CF2 and CF2.

Graphical abstract: Stepwise addition of difluorocarbene to a transition metal centre

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Publication details

The article was received on 05 Nov 2013, accepted on 02 Dec 2013 and first published on 10 Dec 2013


Article type: Communication
DOI: 10.1039/C3CC48468H
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Chem. Commun., 2014,50, 1128-1130

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    Stepwise addition of difluorocarbene to a transition metal centre

    G. M. Lee, D. J. Harrison, I. Korobkov and R. T. Baker, Chem. Commun., 2014, 50, 1128
    DOI: 10.1039/C3CC48468H

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