Selective oxidative conversion of triaryldihydro[C59N]fullerenes: a model case for oxygenation of carbon allotropes

Regina Eigler; Frank W. Heinemann; Andreas Hirsch

doi:10.1039/C3CC48461K

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Selective oxidative conversion of triaryldihydro[C₅₉N]fullerenes: a model case for oxygenation of carbon allotropes†

Regina Eigler,^a Frank W. Heinemann^b and Andreas Hirsch*^a

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* Corresponding authors

^a Department of Chemistry and Pharmacy & Interdisciplinary Center for Molecular Materials (ICMM), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Henkestraße 42, 91054 Erlangen, Germany
E-mail: andreas.hirsch@fau.de
Fax: +49 (0)9131 8526864
Tel: +49 (0)9131 8522537

^b Department of Chemistry and Pharmacy, Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Egerlandstraße 1, 91058 Erlangen, Germany

Abstract

The photooxidation of triaryldihydro[C₅₉N]fullerenes was achieved by treatment with air and light leading to a new selective core functionalization of azafullerenes, which serves as a model case for oxygenation of carbon allotropes.

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Article information

DOI: https://doi.org/10.1039/C3CC48461K
Article type: Communication
Submitted: 05 Nov 2013
Accepted: 19 Dec 2013
First published: 20 Dec 2013

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Chem. Commun., 2014,50, 2021-2023

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Selective oxidative conversion of triaryldihydro[C₅₉N]fullerenes: a model case for oxygenation of carbon allotropes

R. Eigler, F. W. Heinemann and A. Hirsch, Chem. Commun., 2014, 50, 2021 DOI: 10.1039/C3CC48461K

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