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Issue 7, 2014
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A mild and catalyst-free conversion of solid phase benzylidenemalononitrile/benzylidenemalonate to N-benzylidene-amine and its application for fluorescence detection of primary alkyl amine vapor

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Abstract

A new rapid and catalyst-free solid/vapor reaction between benzylidenemalonate/benzylidenemalononitrile and primary alkyl amines was found. With these as sensory units of fluorescent polymers, probes for primary amine vapor with high sensitivity and selectivity were developed.

Graphical abstract: A mild and catalyst-free conversion of solid phase benzylidenemalononitrile/benzylidenemalonate to N-benzylidene-amine and its application for fluorescence detection of primary alkyl amine vapor

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Article information


Submitted
30 Oct 2013
Accepted
12 Nov 2013
First published
13 Nov 2013

Chem. Commun., 2014,50, 872-874
Article type
Communication

A mild and catalyst-free conversion of solid phase benzylidenemalononitrile/benzylidenemalonate to N-benzylidene-amine and its application for fluorescence detection of primary alkyl amine vapor

L. Shi, Y. Fu, C. He, D. Zhu, Y. Gao, Y. Wang, Q. He, H. Cao and J. Cheng, Chem. Commun., 2014, 50, 872
DOI: 10.1039/C3CC48299E

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