Issue 17, 2014
From the journal:

Chemical Communications

A mononuclear cobalt complex with an organic ligand acting as a precatalyst for efficient visible light-driven water oxidation†

Shao Fu,a   Yongdong Liu,a   Yong Ding,*ab   Xiaoqiang Du,a   Fangyuan Song,a   Rui Xianga  and  Baochun Ma*a  

* Corresponding authors

a Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China
E-mail: dingyong1@lzu.edu.cn, mabaochun@lzu.edu.cn

b State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China

Abstract

N,N′-Bis(salicylidene)ethylenediaminecobalt(II) (1) has been investigated as a highly efficient water oxidation precatalyst with a TON of 854 at pH = 9.0, using [Ru(bpy)3](ClO4)2 as a photosensitizer and Na2S2O8 as a sacrificial electron acceptor.

Graphical abstract: A mononuclear cobalt complex with an organic ligand acting as a precatalyst for efficient visible light-driven water oxidation

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Article information

DOI
https://doi.org/10.1039/C3CC48059C
Article type
Communication
Submitted
20 Oct 2013
Accepted
30 Dec 2013
First published
03 Jan 2014

Chem. Commun., 2014,50, 2167-2169

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A mononuclear cobalt complex with an organic ligand acting as a precatalyst for efficient visible light-driven water oxidation

S. Fu, Y. Liu, Y. Ding, X. Du, F. Song, R. Xiang and B. Ma, Chem. Commun., 2014, 50, 2167 DOI: 10.1039/C3CC48059C

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