Issue 10, 2014
From the journal:

Chemical Communications

The effect of the size of surface Pd island ensembles on electron transfer of adsorbed perchlorate ions on Au(111)†

Chen Wu,‡a   Feng Xu,‡b   Martin R. Castella  and  S. C. Edman Tsang*b  

* Corresponding authors

a Department of Materials, University of Oxford, Oxford, OX1 3PH, UK

b Department of Chemistry, University of Oxford, Oxford, OX1 3QR, UK
E-mail: edman.tsang@chem.ox.ac.uk

Abstract

A progressive increase in the size of Pd ensembles on a mica-supported Au(111) single crystal surface can facilitate electron transfer of perchlorate ions at lower anodic potential in CV curves than pure Au(111) due to a strong ligand effect and Pd–Au neighbouring pairs at edge sites render a higher degree of electron transfer.

Graphical abstract: The effect of the size of surface Pd island ensembles on electron transfer of adsorbed perchlorate ions on Au(111)

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Article information

DOI
https://doi.org/10.1039/C3CC48038K
Article type
Communication
Submitted
18 Oct 2013
Accepted
20 Nov 2013
First published
21 Nov 2013

Chem. Commun., 2014,50, 1198-1201

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The effect of the size of surface Pd island ensembles on electron transfer of adsorbed perchlorate ions on Au(111)

C. Wu, F. Xu, M. R. Castell and S. C. E. Tsang, Chem. Commun., 2014, 50, 1198 DOI: 10.1039/C3CC48038K

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