Issue 25, 2014

Enhanced stereoselectivity in a di-Ru(ii) complex of an achiral bis-bidentate ligand

Abstract

The diastereoselective formation of a meso-dinuclear Ru(II) complex of a novel bis-bidentate ligand is reported along with its electrochemical and photophysical properties. The design of the ligand, with its parallel coordination vectors, induces a diastereoselectivity of 1 : 13 : 1 [ΛΛ : (ΛΔ or ΔΛ) : ΔΔ] for the dinuclear complex.

Graphical abstract: Enhanced stereoselectivity in a di-Ru(ii) complex of an achiral bis-bidentate ligand

Supplementary files

Article information

Article type
Communication
Submitted
13 Oct 2013
Accepted
22 Dec 2013
First published
24 Dec 2013

Chem. Commun., 2014,50, 3303-3305

Author version available

Enhanced stereoselectivity in a di-Ru(II) complex of an achiral bis-bidentate ligand

A. K. Pal, P. D. Ducharme and G. S. Hanan, Chem. Commun., 2014, 50, 3303 DOI: 10.1039/C3CC47856D

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