Issue 40, 2014

Spectroscopic characterization of a phenolate bound FeII–O2 adduct: gauging the relative “push” effect of a phenolate axial ligand

Abstract

Dioxygen adducts of solvent, imidazole and phenolate bound iron porphyrin complexes are reported. The data show that the Fe–O vibration of the Fe–O2 species shifts from 584 cm−1 to 570 cm−1 as neutral axial ligands are replaced by the anionic phenolate ligand.

Graphical abstract: Spectroscopic characterization of a phenolate bound FeII–O2 adduct: gauging the relative “push” effect of a phenolate axial ligand

Supplementary files

Article information

Article type
Communication
Submitted
01 Oct 2013
Accepted
31 Oct 2013
First published
31 Oct 2013

Chem. Commun., 2014,50, 5218-5220

Spectroscopic characterization of a phenolate bound FeII–O2 adduct: gauging the relative “push” effect of a phenolate axial ligand

P. K. Das, K. Mittra and A. Dey, Chem. Commun., 2014, 50, 5218 DOI: 10.1039/C3CC47528J

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