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Issue 40, 2014
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Oxidative C(sp3)–H bond cleavage, C–C and C[double bond, length as m-dash]C coupling at a boron center with O2 as the oxidant mediated by platinum(ii)

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Abstract

Dimethyl- and diphenylplatinum(II) fragments PtIIR2 (R = Me, Ph) enable facile and efficient oxidative C(sp3)–H bond cleavage and stepwise C–C and C[double bond, length as m-dash]C coupling at the boron atom of a coordinated 1,5-cyclooctanediyldi(2-pyridyl)borato ligand with O2 as the sole oxidant.

Graphical abstract: Oxidative C(sp3)–H bond cleavage, C–C and C [[double bond, length as m-dash]] C coupling at a boron center with O2 as the oxidant mediated by platinum(ii)

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Article information


Submitted
29 Sep 2013
Accepted
08 Nov 2013
First published
11 Nov 2013

Chem. Commun., 2014,50, 5376-5378
Article type
Communication
Author version available

Oxidative C(sp3)–H bond cleavage, C–C and C[double bond, length as m-dash]C coupling at a boron center with O2 as the oxidant mediated by platinum(II)

S. Pal, P. Y. Zavalij and A. N. Vedernikov, Chem. Commun., 2014, 50, 5376
DOI: 10.1039/C3CC47445C

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