Issue 2, 2014
From the journal:

Chemical Communications

Phosphaalkene vs. phosphinidene: the nature of the P–C bond in carbonyl-decorated carbene → PPh adducts†

Roberta R. Rodrigues,a   Christopher L. Dorsey,a   Chelsee A. Arceneauxa  and  Todd W. Hudnall*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, Texas State University, San Marcos, TX, USA
E-mail: hudnall@txstate.edu

Abstract

Treatment of dichlorophenylphosphine with two equivalents of carbonyl-decorated carbenes results in a two-electron reduction of the phosphorus centre concomitant with carbene oxidation to afford novel phosphaalkenes as confirmed via crystallographic, spectroscopic, and DFT analyses.

Graphical abstract: Phosphaalkene vs. phosphinidene: the nature of the P–C bond in carbonyl-decorated carbene → PPh adducts

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Article information

DOI
https://doi.org/10.1039/C3CC45134H
Article type
Communication
Submitted
08 Jul 2013
Accepted
30 Jul 2013
First published
31 Jul 2013

Chem. Commun., 2014,50, 162-164

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Phosphaalkene vs. phosphinidene: the nature of the P–C bond in carbonyl-decorated carbene → PPh adducts

R. R. Rodrigues, C. L. Dorsey, C. A. Arceneaux and T. W. Hudnall, Chem. Commun., 2014, 50, 162 DOI: 10.1039/C3CC45134H

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