Issue 98, 2013
From the journal:

Chemical Communications

Simple one-pot regioselective 6-O-phosphorylation of carbohydrates and trehalose desymmetrization†

A. Abragam Joseph,ab   Chun-Wei Changa  and  Cheng-Chung Wang*a  

* Corresponding authors

a Institute of Chemistry, Academia Sinica, Taipei 115, Taiwan
E-mail: wangcc@chem.sinica.edu.tw
Fax: +886-2-2783-1237
Tel: +886-2-2789-8618

b Department of Chemistry, National Tsing Hua University, Hsinchu 300, Taiwan

Abstract

Biologically essential carbohydrate 6-phosphates, especially trehalose 6-phosphate, can be synthesized easily in excellent overall yields in 2 steps involving minimum protecting group manipulations. We can cleave the diphenylphosphate group for further synthetic objectives.

Graphical abstract: Simple one-pot regioselective 6-O-phosphorylation of carbohydrates and trehalose desymmetrization

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Article information

DOI
https://doi.org/10.1039/C3CC47180B
Article type
Communication
Submitted
19 Sep 2013
Accepted
16 Oct 2013
First published
17 Oct 2013

Chem. Commun., 2013,49, 11497-11499

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Simple one-pot regioselective 6-O-phosphorylation of carbohydrates and trehalose desymmetrization

A. Abragam Joseph, C. Chang and C. Wang, Chem. Commun., 2013, 49, 11497 DOI: 10.1039/C3CC47180B

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