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Issue 94, 2013
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Copper-catalyzed ortho-halogenation of protected anilines

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Abstract

A practical Cu-catalyzed direct ortho-halogenation of anilines under aerobic conditions has been developed. The reaction shows typically excellent mono-substitution selectivity, high ortho-regiocontrol and large functional group tolerance.

Graphical abstract: Copper-catalyzed ortho-halogenation of protected anilines

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Publication details

The article was received on 19 Sep 2013, accepted on 05 Oct 2013 and first published on 07 Oct 2013


Article type: Communication
DOI: 10.1039/C3CC47174H
Chem. Commun., 2013,49, 11044-11046

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    Copper-catalyzed ortho-halogenation of protected anilines

    B. Urones, Á. M. Martínez, N. Rodríguez, R. G. Arrayás and J. C. Carretero, Chem. Commun., 2013, 49, 11044
    DOI: 10.1039/C3CC47174H

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