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Issue 92, 2013
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A 4-coordinate Ru(ii) imido: unusual geometry, synthesis, and reactivity

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Abstract

A 4-coordinate Ru(II) imido complex, Ru(NAr)(PMe3)3 (1), can be prepared from cis-RuCl2(PMe3)4 and LiNHAr. The structure of the imido is perhaps best described as a flat-based trigonal pyramid with the imido in the equatorial plane. A possible explanation for the unusual geometry is discussed, along with some reactivity of 1.

Graphical abstract: A 4-coordinate Ru(ii) imido: unusual geometry, synthesis, and reactivity

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Article information


Submitted
28 Aug 2013
Accepted
03 Oct 2013
First published
14 Oct 2013

Chem. Commun., 2013,49, 10799-10801
Article type
Communication

A 4-coordinate Ru(II) imido: unusual geometry, synthesis, and reactivity

A. K. Singh, B. G. Levine, R. J. Staples and A. L. Odom, Chem. Commun., 2013, 49, 10799
DOI: 10.1039/C3CC46596A

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