Issue 98, 2013
From the journal:

Chemical Communications

A mechanistic investigation of hydrodehalogenation using ESI-MS†

Zohrab Ahmadia  and  J. Scott McIndoe*a  

* Corresponding authors

a Department of Chemistry, University of Victoria, P.O. Box 3065, Victoria, BC V8W3V6, Canada
E-mail: mcindoe@uvic.ca
Fax: +1-250-721-7147
Tel: +1-250-721-7181

Abstract

The rate of hydrodehalogenation of aryl iodides with a palladium catalyst in methanol exhibits a strong primary kinetic isotope effect from both CD3OD and CH3OD, suggesting that deprotonation plays a major role in the mechanism.

Graphical abstract: A mechanistic investigation of hydrodehalogenation using ESI-MS

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Article information

DOI
https://doi.org/10.1039/C3CC46271D
Article type
Communication
Submitted
15 Aug 2013
Accepted
22 Oct 2013
First published
22 Oct 2013
This article is Open Access
Creative Commons BY license

Chem. Commun., 2013,49, 11488-11490

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A mechanistic investigation of hydrodehalogenation using ESI-MS

Z. Ahmadi and J. S. McIndoe, Chem. Commun., 2013, 49, 11488 DOI: 10.1039/C3CC46271D

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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