Issue 90, 2013
From the journal:

Chemical Communications

Intercalation of chiral molecules into layered metal–organic frameworks: a strategy to synthesize homochiral MOFs†

Yuehong Wen,a   Tianlu Sheng,a   Shengmin Hu,a   Xiao Ma,a   Chunhong Tan,a   Yanlong Wang,a   Zhihao Sun,a   Zhenzhen Xuea  and  Xintao Wu*a  

* Corresponding authors

a State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, China
E-mail: wxt@fjirsm.ac.cn
Fax: +86-591-83719238
Tel: +86-591-83719238

Abstract

Two homochiral SHG MOFs with remarkable layered architectures were prepared by intercalation of (S or R)-5-oxopyrrolidine-2-carboxylate into layered MOFs assembled from hydrogenated Schiff base L and Zn(II). This is a novel strategy to design and synthesize homochiral coordination polymers and potential nonlinear optical materials.

Graphical abstract: Intercalation of chiral molecules into layered metal–organic frameworks: a strategy to synthesize homochiral MOFs

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Supplementary files

Article information

DOI
https://doi.org/10.1039/C3CC46230G
Article type
Communication
Submitted
15 Aug 2013
Accepted
18 Sep 2013
First published
19 Sep 2013

Chem. Commun., 2013,49, 10644-10646

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Intercalation of chiral molecules into layered metal–organic frameworks: a strategy to synthesize homochiral MOFs

Y. Wen, T. Sheng, S. Hu, X. Ma, C. Tan, Y. Wang, Z. Sun, Z. Xue and X. Wu, Chem. Commun., 2013, 49, 10644 DOI: 10.1039/C3CC46230G

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