Issue 92, 2013
From the journal:

Chemical Communications

Photocatalytic oxidation of stilbene by self-assembled stacks of manganese porphyrins†

Miriam de Torres,a   Richard van Hameren,a   Roeland J. M. Nolte,a   Alan E. Rowana  and  Johannes A. A. W. Elemans*a  

* Corresponding authors

a Radboud University Nijmegen, Institute for Molecules and Materials, Heyendaalseweg 135, Nijmegen, The Netherlands
E-mail: J.Elemans@science.ru.nl
Fax: +31 243652190
Tel: +31 243653099

Abstract

Self-assembled stacks of trimeric manganese porphyrins exhibit high activity in the photocatalytic epoxidation of stilbene using O2 as the oxidant. The supramolecular structure of the catalyst leads to increased stability of the system and enhances the stereoselectivity of the reaction.

Graphical abstract: Photocatalytic oxidation of stilbene by self-assembled stacks of manganese porphyrins

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Article information

DOI
https://doi.org/10.1039/C3CC45608K
Article type
Communication
Submitted
23 Jul 2013
Accepted
30 Sep 2013
First published
30 Sep 2013

Chem. Commun., 2013,49, 10787-10789

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Photocatalytic oxidation of stilbene by self-assembled stacks of manganese porphyrins

M. de Torres, R. van Hameren, R. J. M. Nolte, A. E. Rowan and J. A. A. W. Elemans, Chem. Commun., 2013, 49, 10787 DOI: 10.1039/C3CC45608K

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