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Issue 82, 2013
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A perfluorous polyphenyl dendritic shell for the protection of a photosensitizing porphyrazine core

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Abstract

The implementation of thirty-two pentafluorophenyl groups in the periphery of a phthalocyanine analogue results in a photosensitizer with a pronounced resistance towards autophotooxidation. The synthesis relies on the microwave-assisted cycloaddition of terminal alkynes to tetrakis(pentafluorophenyl)cyclopentadienone, for which a new route was devised.

Graphical abstract: A perfluorous polyphenyl dendritic shell for the protection of a photosensitizing porphyrazine core

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Publication details

The article was received on 18 Jul 2013, accepted on 15 Aug 2013 and first published on 15 Aug 2013


Article type: Communication
DOI: 10.1039/C3CC45442H
Chem. Commun., 2013,49, 9413-9415

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    A perfluorous polyphenyl dendritic shell for the protection of a photosensitizing porphyrazine core

    P. Löser, A. Winzenburg and R. Faust, Chem. Commun., 2013, 49, 9413
    DOI: 10.1039/C3CC45442H

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