Issue 84, 2013
From the journal:

Chemical Communications

Catalytic cross deoxygenative and dehydrogenative coupling of aldehydes and alkenes: a redox-neutral process to produce skipped dienes†

Bo Qian,a   Guoying Zhang,a   Yongzheng Dinga  and  Hanmin Huang*a  

* Corresponding authors

a State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, China
E-mail: hmhuang@licp.cas.cn
Fax: +86 931-496-8129

Abstract

A novel catalytic cross deoxygenative and dehydrogenative coupling reaction of aldehydes and alkenes was established via a cooperative catalysis approach. This transformation provided an efficient and atom-economic protocol for the synthesis of 1,4-skipped dienes from aldehydes and simple alkenes under oxidant-free reaction conditions.

Graphical abstract: Catalytic cross deoxygenative and dehydrogenative coupling of aldehydes and alkenes: a redox-neutral process to produce skipped dienes

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Article information

DOI
https://doi.org/10.1039/C3CC45428B
Article type
Communication
Submitted
18 Jul 2013
Accepted
26 Aug 2013
First published
29 Aug 2013

Chem. Commun., 2013,49, 9839-9841

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Catalytic cross deoxygenative and dehydrogenative coupling of aldehydes and alkenes: a redox-neutral process to produce skipped dienes

B. Qian, G. Zhang, Y. Ding and H. Huang, Chem. Commun., 2013, 49, 9839 DOI: 10.1039/C3CC45428B

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