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Issue 83, 2013
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Ruthenium-catalyzed oxidative ortho-benzoxylation of acetanilides with aromatic acids

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Abstract

Substituted acetanilides reacted with aromatic acids in the presence of [{RuCl2(p-cymene)}2], AgSbF6 and (NH4)2S2O8 in ClCH2CH2Cl at 100 °C for 24 h yielding ortho-benzoxylated acetanilides in good to excellent yields in a highly regioselective manner via C–H bond activation.

Graphical abstract: Ruthenium-catalyzed oxidative ortho-benzoxylation of acetanilides with aromatic acids

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Article information


Submitted
15 Jul 2013
Accepted
22 Aug 2013
First published
22 Aug 2013

Chem. Commun., 2013,49, 9651-9653
Article type
Communication

Ruthenium-catalyzed oxidative ortho-benzoxylation of acetanilides with aromatic acids

K. Padala and M. Jeganmohan, Chem. Commun., 2013, 49, 9651
DOI: 10.1039/C3CC45350B

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