Issue 77, 2013

Developing catalytic applications of cooperative bimetallics: competitive hydroamination/trimerization reactions of isocyanates catalysed by sodium magnesiates

Abstract

Mixed-metal reagents [NaMg(CH2SiMe3)3] (1) and [(THF)NaMg(NPh2)3(THF)] [3-(THF)2] can act as precatalysts to selectively promote the hydroamination/trimerization of isocyanates (RNCO) depending on the steric bulk of the R substituent.

Graphical abstract: Developing catalytic applications of cooperative bimetallics: competitive hydroamination/trimerization reactions of isocyanates catalysed by sodium magnesiates

Supplementary files

Article information

Article type
Communication
Submitted
09 Jul 2013
Accepted
20 Jul 2013
First published
22 Jul 2013

Chem. Commun., 2013,49, 8659-8661

Developing catalytic applications of cooperative bimetallics: competitive hydroamination/trimerization reactions of isocyanates catalysed by sodium magnesiates

A. Hernán-Gómez, T. D. Bradley, A. R. Kennedy, Z. Livingstone, S. D. Robertson and E. Hevia, Chem. Commun., 2013, 49, 8659 DOI: 10.1039/C3CC45167D

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