Spin polarization in electrodeposited thin films of the molecule-based magnetic semiconductor Cr5.5(CN)12·11.5H2O

Eugenio Coronado; Juan P. Prieto-Ruiz; Helena Prima-Garcia

doi:10.1039/C3CC45036H

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Spin polarization in electrodeposited thin films of the molecule-based magnetic semiconductor Cr_5.5(CN)₁₂·11.5H₂O†

Eugenio Coronado,*^a Juan P. Prieto-Ruiz^a and Helena Prima-Garcia*^a

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* Corresponding authors

^a Instituto de Ciencia Molecular (ICMol), Universitat de València, C/Catedrático José Beltrán, 2, 46980-Paterna, Spain
E-mail: helena.prima@uv.es, eugenio.coronado@uv.es

Abstract

The magnetoresistance (MR) effect of thin films of the Prussian Blue Analogue (PBA) Cr_5.5(CN)₁₂·11.5H₂O, prepared by electrochemical deposition, has been measured using the standard two-point probe method. This molecule-based ferrimagnetic material, with a T_c = 240 K, exhibits MR up to 2% at 6 T and 200 K.

This article is part of the themed collection: Molecular Spintronics

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Article information

DOI: https://doi.org/10.1039/C3CC45036H
Article type: Communication
Submitted: 04 Jul 2013
Accepted: 27 Aug 2013
First published: 03 Sep 2013

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Chem. Commun., 2013,49, 10145-10147

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Spin polarization in electrodeposited thin films of the molecule-based magnetic semiconductor Cr_5.5(CN)₁₂·11.5H₂O

E. Coronado, J. P. Prieto-Ruiz and H. Prima-Garcia, Chem. Commun., 2013, 49, 10145 DOI: 10.1039/C3CC45036H

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