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Issue 84, 2013
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The evolution of spin distribution in the photoexcited triplet state of ethyne-elaborated porphyrins

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Abstract

Ethyne elaboration of a (porphinato)Zn(II) (PZn) chromophoric core renders fine control over the zero-field splitting (ZFS) parameters of the lowest energy photoexcited triplet state (T1), resulting in the ability to manipulate the spin distribution and establish highly symmetrical coincident optical and magnetic principal axes.

Graphical abstract: The evolution of spin distribution in the photoexcited triplet state of ethyne-elaborated porphyrins

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Article information


Submitted
30 Jun 2013
Accepted
13 Aug 2013
First published
13 Aug 2013

Chem. Commun., 2013,49, 9722-9724
Article type
Communication

The evolution of spin distribution in the photoexcited triplet state of ethyne-elaborated porphyrins

P. J. Angiolillo, J. Rawson, P. R. Frail and M. J. Therien, Chem. Commun., 2013, 49, 9722
DOI: 10.1039/C3CC44903C

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