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Issue 73, 2013
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Hexagonal molecular “palladawheel”

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Abstract

A hexagonal molecular “palladawheel” consisting of six N,N’-diphenyl-2,6-pyridinedicarboxamide–Pd(II) pincer complexes held together via six Pd⋯O[double bond, length as m-dash]CAmide bonds was efficiently synthesized and crystallographically characterized. The hexameric ring possesses C3 (pseudo-S6) symmetry with up-down alternating phenyl substituents acting as interior “spokes” and exterior “propellers.”

Graphical abstract: Hexagonal molecular “palladawheel”

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Publication details

The article was received on 23 Jun 2013, accepted on 21 Jul 2013 and first published on 22 Jul 2013


Article type: Communication
DOI: 10.1039/C3CC44714F
Chem. Commun., 2013,49, 8042-8044

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    Hexagonal molecular “palladawheel”

    Q. Wang, V. W. Day and K. Bowman-James, Chem. Commun., 2013, 49, 8042
    DOI: 10.1039/C3CC44714F

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