Jump to main content
Jump to site search

Issue 85, 2013
Previous Article Next Article

Heterometallic clusters with a new {Re3Mo3S8} core: direct synthesis, properties and DFT calculations

Author affiliations

Abstract

We report the direct facile high-temperature synthesis and investigation of heterometallic rhenium–molybdenum cluster K6[Re3Mo3S8(CN)4(CN)2/2] (1) with a new {Re3Mo3S8} core. Dissolution of polymeric compound 1 resulted in subsequent oxidation and formation of stable 23e paramagnetic anionic cluster complex [Re3Mo3S8(CN)6]6−.

Graphical abstract: Heterometallic clusters with a new {Re3Mo3S8} core: direct synthesis, properties and DFT calculations

Back to tab navigation

Supplementary files

Article information


Submitted
20 Jun 2013
Accepted
28 Aug 2013
First published
03 Sep 2013

Chem. Commun., 2013,49, 10019-10021
Article type
Communication

Heterometallic clusters with a new {Re3Mo3S8} core: direct synthesis, properties and DFT calculations

Y. M. Gayfulin, N. G. Naumov, M. R. Rizhikov, A. I. Smolentsev, V. A. Nadolinny and Y. V. Mironov, Chem. Commun., 2013, 49, 10019
DOI: 10.1039/C3CC44643C

Social activity

Search articles by author

Spotlight

Advertisements