Issue 70, 2013
From the journal:

Chemical Communications

Nickel-catalyzed manipulation of tertiary phosphinesvia highly selective C–P bond cleavage†

Jian Cao,a   Xian Huang‡ab  and  Luling Wu*a  

* Corresponding authors

a Department of Chemistry, Zhejiang University, Hangzhou 310028, P. R. China
E-mail: wululing@zju.edu.cn

b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, P. R. China

Abstract

A catalytic cycle involving oxidative addition of nickel(0) with a carbon–carbon single bond in the three-membered ring of diarylmethylenecyclopropa[b]naphthalenes, highly selective cleavage of the C–P bond, and migration of the aryl group of phosphine consequently provides a new type of bulky phosphine in excellent yields.

Graphical abstract: Nickel-catalyzed manipulation of tertiary phosphines via highly selective C–P bond cleavage

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Article information

DOI
https://doi.org/10.1039/C3CC43640C
Article type
Communication
Submitted
15 May 2013
Accepted
01 Jul 2013
First published
02 Jul 2013

Chem. Commun., 2013,49, 7747-7749

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Nickel-catalyzed manipulation of tertiary phosphines via highly selective C–P bond cleavage

J. Cao, X. Huang and L. Wu, Chem. Commun., 2013, 49, 7747 DOI: 10.1039/C3CC43640C

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