Issue 72, 2013
From the journal:

Chemical Communications

A novel copper containing photoinitiator, copper(ii) acylphosphinate, and its application in both the photomediated CuAAC reaction and in atom transfer radical polymerization†

Tao Gong,a   Brian J. Adzimaa  and  Christopher N. Bowman*a  

* Corresponding authors

a Department of Chemical and Biological Engineering, University of Colorado at Boulder, Boulder, CO 80309-0596, USA
E-mail: christopher.bowman@colorado.edu
Fax: +1-303-492-4341
Tel: +1-303-492-3247

Abstract

A novel copper(II) complex has been developed in which the counter anion, acylphosphinate, serves as a visible light photoinitiator. This molecule is inactive in the dark but, upon visible light exposure, both CuAAC and ATRP reactions are readily and rapidly initiated.

Graphical abstract: A novel copper containing photoinitiator, copper(ii) acylphosphinate, and its application in both the photomediated CuAAC reaction and in atom transfer radical polymerization

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C3CC43637C
Article type
Communication
Submitted
15 May 2013
Accepted
24 Jul 2013
First published
25 Jul 2013

Chem. Commun., 2013,49, 7950-7952

Permissions

Request permissions

A novel copper containing photoinitiator, copper(II) acylphosphinate, and its application in both the photomediated CuAAC reaction and in atom transfer radical polymerization

T. Gong, B. J. Adzima and C. N. Bowman, Chem. Commun., 2013, 49, 7950 DOI: 10.1039/C3CC43637C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements