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Issue 74, 2013
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A homochiral porous metal–organic framework for enantioselective adsorption of mandelates and photocyclizaton of tropolone ethers

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Abstract

A chiral porous metal–organic framework of an axially C2-symmetric 1,1′-biphenol ligand is constructed and can be used as a solid-state host to enanioselectively adsorb mandelates with up to 93.1% ee and to entrap achiral tropolone ethers and induce their asymmetric photocyclization with up to 98.5% ee.

Graphical abstract: A homochiral porous metal–organic framework for enantioselective adsorption of mandelates and photocyclizaton of tropolone ethers

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Article information


Submitted
12 May 2013
Accepted
15 Jul 2013
First published
16 Jul 2013

Chem. Commun., 2013,49, 8253-8255
Article type
Communication

A homochiral porous metal–organic framework for enantioselective adsorption of mandelates and photocyclizaton of tropolone ethers

Y. Peng, T. Gong and Y. Cui, Chem. Commun., 2013, 49, 8253
DOI: 10.1039/C3CC43549K

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