Jump to main content
Jump to site search
Access to RSC content Close the message box

Continue to access RSC content when you are not at your institution. Follow our step-by-step guide.


Issue 67, 2013
Previous Article Next Article

Ligand effects of NHC–iridium catalysts for signal amplification by reversible exchange (SABRE)

Author affiliations

Abstract

SABRE hyperpolarizes substrates by polarization transfer from para-hydrogen in a metal complex. We have measured the signal enhancement of pyridine and its exchange rate in various [Ir(NHC)(Py)3(H)2]+ complexes to gain insight into their dependence on the N-Heterocyclic Carbene (NHC) ligand's steric and electronic properties.

Graphical abstract: Ligand effects of NHC–iridium catalysts for signal amplification by reversible exchange (SABRE)

Back to tab navigation

Supplementary files

Article information


Submitted
08 May 2013
Accepted
26 Jun 2013
First published
27 Jun 2013

This article is Open Access

Chem. Commun., 2013,49, 7388-7390
Article type
Communication

Ligand effects of NHC–iridium catalysts for signal amplification by reversible exchange (SABRE)

B. J. A. van Weerdenburg, S. Glöggler, N. Eshuis, A. H. J. (. Engwerda, J. M. M. Smits, R. de Gelder, S. Appelt, S. S. Wymenga, M. Tessari, M. C. Feiters, B. Blümich and F. P. J. T. Rutjes, Chem. Commun., 2013, 49, 7388
DOI: 10.1039/C3CC43423K

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Material from this article can be used in other publications provided that the correct acknowledgement is given with the reproduced material.

Reproduced material should be attributed as follows:

  • For reproduction of material from NJC:
    [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the Centre National de la Recherche Scientifique (CNRS) and the RSC.
  • For reproduction of material from PCCP:
    [Original citation] - Published by the PCCP Owner Societies.
  • For reproduction of material from PPS:
    [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the European Society for Photobiology, the European Photochemistry Association, and RSC.
  • For reproduction of material from all other RSC journals:
    [Original citation] - Published by The Royal Society of Chemistry.

Information about reproducing material from RSC articles with different licences is available on our Permission Requests page.


Social activity

Search articles by author

Spotlight

Advertisements