Issue 64, 2013
From the journal:

Chemical Communications

Chiral microporous Ti(salan)-based metal–organic frameworks for asymmetric sulfoxidation†

Chengfeng Zhu,a   Xu Chen,a   Zhiwei Yang,a   Xia Du,a   Yan Liu*a  and  Yong Cui*a  

* Corresponding authors

a School of Chemistry and Chemical Technology and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, China
E-mail: yongcui@sjtu.edu.cn, yanliu.sh@gmail.com
Fax: +86 21-5474-1297

Abstract

Chiral porous metal–metallosalan frameworks are constructed from an unsymmetrical chiral pyridinecarboxylate ligand derived from Ti(salan) and are shown to be heterogeneous catalysts for asymmetric oxidation of thioethers to sulfoxides.

Graphical abstract: Chiral microporous Ti(salan)-based metal–organic frameworks for asymmetric sulfoxidation

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Article information

DOI
https://doi.org/10.1039/C3CC43225D
Article type
Communication
Submitted
01 May 2013
Accepted
17 Jun 2013
First published
08 Jul 2013

Chem. Commun., 2013,49, 7120-7122

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Chiral microporous Ti(salan)-based metal–organic frameworks for asymmetric sulfoxidation

C. Zhu, X. Chen, Z. Yang, X. Du, Y. Liu and Y. Cui, Chem. Commun., 2013, 49, 7120 DOI: 10.1039/C3CC43225D

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