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Issue 67, 2013
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Flexibility of ZIF-8 materials studied using 129Xe NMR

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Abstract

Structural changes in a porous hybrid inorganic–organic ZIF-8 compound have been explored using hyperpolarized 129Xe NMR of adsorbed xenon at various temperatures. Upon xenon adsorption at low temperature, the organic linkers undergo a reorientation leading to a stepwise increase in xenon adsorption and in chemical shift.

Graphical abstract: Flexibility of ZIF-8 materials studied using 129Xe NMR

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Article information


Submitted
26 Apr 2013
Accepted
18 Jun 2013
First published
19 Jun 2013

Chem. Commun., 2013,49, 7403-7405
Article type
Communication

Flexibility of ZIF-8 materials studied using 129Xe NMR

M. Springuel-Huet, A. Nossov, F. Guenneau and A. Gédéon, Chem. Commun., 2013, 49, 7403
DOI: 10.1039/C3CC43119C

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