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Issue 56, 2013
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One-pot synthesis of sterically congested large aromatic hydrocarbonsvia 1,4-diphenyl-2,3-triphenylyne

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Abstract

Large polyarenes with unusually complex structures can be obtained in a straightforward manner from commercially available starting materials, by means of aryne chemistry. This approach involves a sequence of tandem reactions that can be performed in one pot to give sterically congested chiral aromatic hydrocarbons that adopt highly twisted conformations.

Graphical abstract: One-pot synthesis of sterically congested large aromatic hydrocarbons via 1,4-diphenyl-2,3-triphenylyne

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Article information


Submitted
26 Apr 2013
Accepted
17 May 2013
First published
20 May 2013

Chem. Commun., 2013,49, 6274-6276
Article type
Communication

One-pot synthesis of sterically congested large aromatic hydrocarbons via 1,4-diphenyl-2,3-triphenylyne

D. Rodríguez-Lojo, D. Pérez, D. Peña and E. Guitián, Chem. Commun., 2013, 49, 6274
DOI: 10.1039/C3CC43103G

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