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Issue 78, 2013
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Ru-catalyzed 1,4-addition of arylboronic acids to acrylic acid derivatives in the presence of phenols

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Abstract

[Ru(p-cymene)Cl2]2-catalyzed 1,4-addition reactions between arylboronic acids and butyl acrylate and acrylamide in the presence of phenols were investigated, good to excellent yields were obtained. The addition of phenols remarkably promoted the protonolysis and inhibited the β-H elimination of the 1,4-addition intermediates, and also efficiently suppressed the protonolysis of arylboronic acids.

Graphical abstract: Ru-catalyzed 1,4-addition of arylboronic acids to acrylic acid derivatives in the presence of phenols

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Publication details

The article was received on 26 Apr 2013, accepted on 30 Jul 2013 and first published on 31 Jul 2013


Article type: Communication
DOI: 10.1039/C3CC43095B
Chem. Commun., 2013,49, 8797-8799

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    Ru-catalyzed 1,4-addition of arylboronic acids to acrylic acid derivatives in the presence of phenols

    L. Zhang, X. Xie, Z. Peng, L. Fu and Z. Zhang, Chem. Commun., 2013, 49, 8797
    DOI: 10.1039/C3CC43095B

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