Issue 80, 2013

Hydrogenation of nitroarenes using defined iron–phosphine catalysts

Abstract

A novel iron-catalyzed hydrogenation of nitroarenes to the corresponding amines is reported. An in situ combination of Fe(BF4)2·6H2O and phosphine allows for highly selective hydrogenation of a broad range of aromatic and nitroarenes tolerating different functional groups.

Graphical abstract: Hydrogenation of nitroarenes using defined iron–phosphine catalysts

Supplementary files

Article information

Article type
Communication
Submitted
11 Jun 2013
Accepted
17 Jul 2013
First published
18 Jul 2013

Chem. Commun., 2013,49, 9089-9091

Hydrogenation of nitroarenes using defined iron–phosphine catalysts

G. Wienhöfer, M. Baseda-Krüger, C. Ziebart, F. A. Westerhaus, W. Baumann, R. Jackstell, K. Junge and M. Beller, Chem. Commun., 2013, 49, 9089 DOI: 10.1039/C3CC42983K

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