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Issue 61, 2013
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Carbonylation of the simplest persistent diaminocarbene

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Abstract

The reactions of the acyclic diaminocarbenes (Me2N)2C and (Ph2N)(iPr2N)C with CO proceed in a 2 : 1 stoichiometric ratio, affording unprecedented betainic oxyallyl species of type [(R2N)2C]2CO.

Graphical abstract: Carbonylation of the simplest persistent diaminocarbene

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Article information


Submitted
18 Apr 2013
Accepted
11 May 2013
First published
13 May 2013

Chem. Commun., 2013,49, 6834-6836
Article type
Communication

Carbonylation of the simplest persistent diaminocarbene

T. Schulz, C. Färber, M. Leibold, C. Bruhn, W. Baumann, D. Selent, T. Porsch, M. C. Holthausen and U. Siemeling, Chem. Commun., 2013, 49, 6834
DOI: 10.1039/C3CC42888E

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