Graphene oxide grafted with Pd17Se15 nano-particles generated from a single source precursor as a recyclable and efficient catalyst for C–O coupling in O-arylation at room temperature

Hemant Joshi; Kamal Nayan Sharma; Alpesh K. Sharma; Om Prakash; Ajai Kumar Singh

doi:10.1039/C3CC42608D

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Graphene oxide grafted with Pd₁₇Se₁₅ nano-particles generated from a single source precursor as a recyclable and efficient catalyst for C–O coupling in O-arylation at room temperature†

Hemant Joshi,^a Kamal Nayan Sharma,^a Alpesh K. Sharma,^a Om Prakash^a and Ajai Kumar Singh*^a

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* Corresponding authors

^a Department of Chemistry, Indian Institute of Technology Delhi, New Delhi 110016, India
E-mail: aksingh@chemistry.iitd.ac.in, ajai57@hotmail.com
Fax: +91-01-26581102
Tel: +91-011-26591379

Abstract

The Pd₁₇Se₁₅ nanoparticles, synthesized for the first time from a single source precursor [Pd(L)Cl₂] {L = 1,3-bis(phenylselenyl)propan-2-ol} and grafted onto graphene oxide, show high catalytic activity in C–O coupling between aryl/heteroaryl chlorides/bromides and phenol at room temperature (Pd loading 1 mol%; yield up to 94%).

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Article information

DOI: https://doi.org/10.1039/C3CC42608D
Article type: Communication
Submitted: 10 Apr 2013
Accepted: 03 May 2013
First published: 07 May 2013

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Chem. Commun., 2013,49, 7483-7485

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Graphene oxide grafted with Pd₁₇Se₁₅ nano-particles generated from a single source precursor as a recyclable and efficient catalyst for C–O coupling in O-arylation at room temperature

H. Joshi, K. N. Sharma, A. K. Sharma, O. Prakash and A. K. Singh, Chem. Commun., 2013, 49, 7483 DOI: 10.1039/C3CC42608D

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