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Issue 52, 2013
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Palladium-catalysed aerobic oxidative Heck-type alkenylation of Csp3–H for pyrrole synthesis

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Abstract

The first palladium-catalysed aerobic oxidative intramolecular alkenylation of Csp3–H bonds was described. The reaction conditions were mild and molecular oxygen was used as the terminal oxidant. Kinetic studies showed that the Csp3–H metallation step was a slow step.

Graphical abstract: Palladium-catalysed aerobic oxidative Heck-type alkenylation of Csp3–H for pyrrole synthesis

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Supplementary files

Article information


Submitted
29 Mar 2013
Accepted
07 May 2013
First published
09 May 2013

Chem. Commun., 2013,49, 5853-5855
Article type
Communication

Palladium-catalysed aerobic oxidative Heck-type alkenylation of Csp3–H for pyrrole synthesis

L. Meng, K. Wu, C. Liu and A. Lei, Chem. Commun., 2013, 49, 5853
DOI: 10.1039/C3CC42307G

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